Light emitting device

ABSTRACT

The present invention provides a light emitting device, comprising a first light emitting diode for emitting light in an ultraviolet wavelength region; at least one phosphor arranged around the first light emitting diode and excited by the light emitted from the first light emitting diode to emit light having a peak wavelength longer than the wavelength of the light emitted from the first light emitting diode; and at least one second light emitting diode for emitting light having a wavelength different from the peak wavelength of the light emitted from the phosphor. According to the present invention, there is provided a white light emitting device, wherein using a light emitting diode for emitting light different in wavelength from light that is ex-cititively emitted from the phosphor, an excitation light source, i.e., light in the ultraviolet region for exciting the phosphor is effectively used, thereby improving energy conversion efficiency and improving reliability.

CROSS REFERENCE TO RELATED APPLICATIONS

This application is the National Stage of International Application No.PCT/KR2007/004066, filed Aug. 24, 2007, and claims priority from and thebenefit of Korean Patent Application No. 10-2006-0082501, filed on Aug.29, 2006, which are both hereby incorporated by reference for allpurposes as if fully set forth herein.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to a light emitting device, and moreparticularly, to a light emitting device in which an energy conversionefficiency can be improved by using an ultraviolet light emitting diodeas an excitation source of a phosphor.

2. Discussion of the Background

A light emitting diode (LED) refers to a device for emitting lightthrough recombination of minority carriers (electrons or holes) as acompound semiconductor having p-n junction structure. Since the lightemitting diode has characteristics of low power consumption, longlifespan, installability in a narrow space, and strong resistanceagainst vibration, the light emitting diode has been increasingly usedas various illumination devices as well as parts of various informationprocessing and communication applications and has been manufactured asvarious light emitting devices which are suitable to variousapplications. In recent years, white light emitting diodes in additionto single color light emitting devices, such as red, blue or green lightemitting devices, have been placed on the market. As the white lightemitting devices are applied to products for automobiles andillumination, it is expected that their demands will be rapidlyincreased.

In a representative method of implementing a white light emittingdevice, a yellow phosphor is arranged over a blue light emitting diode,so that blue light emitted from the blue light emitting diode and yellowlight emitted from the phosphor which is excited by a portion of theblue light are color-mixed to implement white color. Although such amethod of implementing white light provides a simple configuration andan excellent mass-producibility, there is a problem in that theshortages of green and red spectra may reduce color rendering.

In another representative method of implementing a white light emittingdevice, phosphors, which are excited by ultraviolet ray to emit blue,green and red lights, respectively, are arranged over a light emittingdiode for emitting ultraviolet ray.

Since such a method uses ultraviolet ray, which is a higher excitationlight source than blue light, to emit light having wavelengths from blueto red regions, there is an advantage in that the color rendering ishigher. However, various phosphors, such as blue, green and redphosphors, are used, thereby increasing manufacturing costs.

Specifically, the red phosphor which is generally commercialized issulfide based phosphor. In this case, there is a problem in that thelight emitting device easily reacts with water vapor and carbon dioxidein the atmosphere during its operation and therefore the chemicalcharacteristics of the phosphor is distorted. Since the byproduct ofsuch a reaction, H₂S gas, corrodes metal such as electrodes within thelight emitting device, there is a problem in that the reliability of thelight emitting diode may be reduced.

Further, there is another problem in that the red phosphor has a lowerconversion efficiency for the light emitted under the excitation by theexcitation energy than blue and green phosphors.

SUMMARY OF THE INVENTION

The present invention is conceived to solve the aforementioned problem.An object of the present invention is to provide a white light emittingdevice in which energy conversion efficiency can be improved byeffectively using ultraviolet light as an excitation source ofphosphors.

Another object of the present invention is to provide a white lightemitting device in which a light emitting diode for emitting lightdifferent in wavelength from light excitatively emitted from a phosphorcan be used to improve reliability against vapor and carbon dioxide towhich the light emitting device may be easily exposed.

According to the present invention for achieving the objects, there isprovided a light emitting device, comprising a first light emittingdiode for emitting light in an ultraviolet wavelength region; at leastone phosphor arranged around the first light emitting diode and excitedby the light emitted from the first light emitting diode to emit lighthaving a peak wavelength longer than the wavelength of the light emittedfrom the first light emitting diode; and at least one second lightemitting diode for emitting light having a wavelength different from thepeak wavelength of the light emitted from the phosphor.

The phosphor may be at least any one of silicate based phosphor,germanate based phosphor and germanate-silicate based phosphor, andcontains copper, and the phosphor may further contain lead.

The phosphor may include at least any one of a first phosphor having itspeak wavelength positioned in a range of 410 nm to 500 nm and a secondphosphor having its peak wavelength position in a range of 500 nm to 590nm.

The phosphor may include a silicate based phosphor represented byChemical Formula 1:

a(M^(I)O).b(M^(II)O).c(M^(III)A).d(M^(III) ₂O).e(M^(IV) ₂O₃).f(M^(V)_(o)O_(p)).g(SiO₂).h(M^(VI) _(x)O_(y))

where M^(I) is at least one element selected from the group containingCu and Pb; M^(II) is at least one element selected from the groupconsisting of Be, Mg, Ca, Sr, Ba, Zn, Cd and Mn; M^(III) is at least oneelement selected from the group consisting of Li, Na, K, Rb, Cs, Au andAg; M^(IV) is at least one element selected from the group consisting ofB, Al, Ga and In; M^(V) is at least one element selected from the groupconsisting of Ge, V, Nb, Ta, W, Mo, Ti, Zr and Hf, M^(VI) is at leastone element selected from the group consisting of Bi, Sn, Sb, Sc, Y, La,Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu; A is at leastone element selected from the group consisting of F, Cl, Br and I; a, b,c, d, e, f, g, h, o, p, x and y are set in ranges of 0<a≦2, 0<b≦8,0≦c≦4, 0≦d≦2, 0≦e≦2, 0≦f≦2, 0<g≦10, 0<h≦5, 1≦o≦2, 1≦p≦5, 1≦x≦2, and1≦y≦5.

The phosphor may include a germanate and/or germanate-silicate basedphosphor represented by Chemical Formula 2:

a(M^(I)O).b(M^(II) ₂O).c(M^(II)A).dGeO₂ e(M^(III)O).f(M^(IV)₂O₃).g(M^(V) _(o)O_(p)).h(M^(VI) _(x)O_(y)),

where M^(I) is at least one element selected from the group containingCu and Pb; M^(II) is at least one element selected from the groupconsisting of Li, Na, K, Rb, Cs, Au and Ag; M^(III) is at least oneelement selected from the group consisting of Be, Mg, Ca, Sr, Ba, Zn, Cdand Mn; M^(IV) is at least one element selected from the groupconsisting of Sc, Y, B, Al, Ga, In and La; M^(V) is one or more elementsselected from the group consisting of Si, Ti, Zr, Mn, V, Nd, Ta, W andMo; M^(VI) is at least one element selected from the group consisting ofBi, Sn, Pr, Sm, Eu, Gd, Dy and Tb; A is at least one element selectedfrom the group consisting of F, Cl, Br and I; a, b, c, d, e, f, g, h, o,p, x and y are set in ranges of 0<a≦2, 0≦b≦2, 0≦c≦10, 0<d≦10, 0≦e≦14,0≦f≦14, 0≦g≦10, 0≦h≦2, 1≦o≦2, 1≦p≦5, 1≦x≦2, and 1≦y≦5.

The second light emitting diode may include a light emitting diode foremitting light having a wavelength longer than the peak wavelength ofthe light emitted from the phosphor.

The second light emitting diode may include a light emitting diode foremitting light in a wavelength range of 590 nm to 720 nm.

The second light emitting diode may further include a light emittingdiode for emitting light in a wavelength range of 420 nm to 480 nm whichis shorter than the peak wavelength of the light emitted from thephosphor.

According to the present invention, a white light emitting device can beprovided in which energy conversion efficiency can be improved byeffectively using an ultraviolet light emitting diode as an excitationsource of a phosphor.

Further, a light emitting diode for emitting light different inwavelength from light excitatively emitted from a phosphor can be usedto improve reliability against vapor and carbon dioxide to which thelight emitting device may be easily exposed.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a sectional view showing a first embodiment of a lightemitting device according to the present invention.

FIG. 2 is a sectional view showing a second embodiment of the lightemitting device according to the present invention.

FIG. 3 is a sectional view showing a third embodiment of the lightemitting device according to the present invention.

FIG. 4 is a sectional view showing a fourth embodiment of the lightemitting device according to the present invention.

FIG. 5 is a sectional view showing a fifth embodiment of the lightemitting device according to the present invention.

DETAILED DESCRIPTION OF THE ILLUSTRATED EMBODIMENTS

Hereinafter, a light emitting device according to the present inventionwill be described in detail with reference to the accompanying drawings.

However, the present invention is not limited to a preferred embodimentset forth herein but can be implemented in various forms. In addition,the embodiments are merely provided to allow the present invention to becompletely described herein and to fully convey the scope of theinvention to those skilled in the art. Throughout the drawings, likereference numerals are used to designate like elements.

A light emitting device of the present invention comprises a first lightemitting diode for emitting light in an ultraviolet wavelength region;at least one phosphor arranged around the first light emitting diode andexcited by the light emitted from the first light emitting diode to emitlight having a peak wavelength longer than the wavelength of the lightemitted from the first light emitting diode; and at least one secondlight emitting diode for emitting light having a wavelength differentfrom the peak wavelength of the light emitted from the phosphor, therebyimplementing white light emission.

That is, the light emitting device can be configured in the combinationof a first light emitting diode for emitting ultraviolet ray in awavelength range of 250 nm to 410 nm, a first phosphor for emitting bluelight in a peak wavelength range of 410 nm to 500 nm, at least onesecond phosphor for emitting green and yellow lights in a peakwavelength range of 500 nm to 590 nm, and a second light emitting diodefor emitting red light in a wavelength range of 590 nm to 720 nm.

More preferably, the light emitting device can be configured in thecombination of a first light emitting diode for emitting light in awavelength range of 250 nm to 350 nm, a first phosphor for emitting bluelight in a peak wavelength range of 440 nm to 480 nm, a second phosphorfor emitting green light in a peak wavelength range of 510 nm to 545 nm;and a second light emitting diode for emitting red light in a wavelengthrange of 620 nm to 660 nm.

The phosphor excited by the light having the ultraviolet wavelengthincludes at least any one of silicate based phosphor, germanate basedphosphor and germanate-silicate based phosphor, which contain copper,and may include a phosphor which further contains lead.

The phosphor may be a silicate based phosphor which is represented byChemical Formula of chemistry figure 1:

a(M^(I)O).b(M^(II)O).c(M^(III)A).d(M^(III) ₂O).e(M^(IV) ₂O₃).f(M^(V)_(o)O_(p)).g(SiO₂).h(M^(VI) _(x)O_(y))   [Chemistry Figure 1]

where M^(I) is at least one element selected from the group containingCu and Pb; M^(II) is at least one element selected from the groupconsisting of Be, Mg, Ca, Sr, Ba, Zn, Cd and Mn; M^(III) is at least oneelement selected from the group consisting of Li, Na, K, Rb, Cs, Au andAg; M^(IV) is at least one element selected from the group consisting ofB, Al, Ga and In; M^(V) is at least one element selected from the groupconsisting of Ge, V, Nb, Ta, W, Mo, Ti, Zr and Hf, M^(VI) is at leastone element selected from the group consisting of Bi, Sn, Sb, Sc, Y, La,Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu; A is at leastone element selected from the group consisting of F, Cl, Br and I; a, b,c, d, e, f, g, h, o, p, x and y are set in ranges of 0<a≦2, 0<b≦8,0≦c≦4, 0≦d≦2, 0≦e≦2, 0≦f≦2, 0<g≦10, 0<h≦5, 1≦o≦2, 1≦p≦5, 1≦x≦2, and1≦y≦5.

The phosphor may be a germanate and/or germanate-silicate phosphor whichis represented by Chemical Formula of chemistry figure 2:

a(M^(I)O).b(M^(II) ₂O).c(M^(II)A).dGeO₂ e(M^(III)O).f(M^(IV)₂O₃).g(M^(V) _(o)O_(p)).h(M^(VI) _(x)O_(y)),   [Chemistry Figure 2]

where M^(I) is at least one element selected from the group containingCu and Pb; M^(II) is at least one element selected from the groupconsisting of Li, Na, K, Rb, Cs, Au and Ag; M^(III) is at least oneelement selected from the group consisting of Be, Mg, Ca, Sr, Ba, Zn, Cdand Mn; M^(IV) is at least one element selected from the groupconsisting of Sc, Y, B. Al, Ga, In and La; M^(V) is one or more elementsselected from the group consisting of Si, Ti, Zr, Mn, V, Nd, Ta, W andMo; M^(VI) is at least one element selected from the group consisting ofBi, Sn, Pr, Sm, Eu, Gd, Dy and Tb; A is at least one element selectedfrom the group consisting of F, Cl, Br and I; a, b, c, d, e, f, g, h, o,p, x and y are set in ranges of 0<a≦2, 0≦b≦2, 0≦c≦10, 0<d≦10, 0≦e≦14,0≦f≦14, 0≦g≦10, 0≦h≦2, 1≦o≦2, 1≦p≦5, 1≦x≦2, and 1≦y≦5.

Preferably, the silicate based phosphor is represented by ChemicalFormula 3:

((Ba,Sr,Ca,Mg)_(1-x)(Pb,Cu)_(x))₂SiO₄:Eu,B

where B is at least one element selected from the group consisting ofBi, Sn, Sb, Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb,Lu and Mn; x is set in a range of 0 to 1; and Eu and B are set in rangesof 0 to 0.2, respectively.

Cu_(0.05)Li_(0.002)Sr_(1.5)Ba_(0.448)SiO₄:Gd,Eu   [Chemistry Figure 4]

Cu_(0.2)Ba₂Zn_(0.2)Mg_(0.6)Si₂O_(7:)Eu   [Chemistry Figure 5]

Cu_(0.02)Sr_(0.38)Ba_(0.90)Ca_(0.6)Si_(0.98)Ge_(0.02)O₄:Eu_(0.1)  [Chemistry Figure 6]

The phosphor represented by Chemical Formula 4 emits light having awavelength of 557 nm, the phosphor represented by Chemical Formula 5emits light having a wavelength of 467 nm, and the phosphor representedby Chemical Formula 6 emits light having a wavelength of 563 nm. Assuch, the orthosilicate based phosphor can control its wavelength ofemission light depending on its elements and compositions.

As such, the light emitting device according to the present inventioncomprises a first light emitting diode for emitting light in anultraviolet wavelength region; at least one phosphor arranged around thefirst light emitting diode and excited by the light emitted from thefirst light emitting diode to emit light with a peak wavelength which islonger than the wavelength of the light emitted from the first lightemitting diode, i.e., at least one phosphor for emitting blue, green andyellow lights; and at least one second light emitting diode for emittinglight having a wavelength different from the peak wavelength of thelight emitted from the phosphor, i.e., a red light emitting diode,thereby implementing the white light emission.

Accordingly, as compared with a conventional light emitting device whichincludes an ultraviolet light emitting diode and phosphors for emittingblue, green and red lights, a red light emitting diode is used on behalfof the red phosphor which has a lower conversion efficiency and isexcited by energy of light in an ultraviolet wavelength region as theexcitation light source, thereby improving energy conversion efficiencyof the white light emitting device.

Further, in comparison with the prior art, the phosphor for emitting asmaller amount of blue and green lights is used to implement white lightwith the same intensity, thereby reducing its manufacturing costs.

Also, the red light emitting diode is used to solve the problem that thegenerally commercialized sulfide based red phosphor easily reacts withvapor and carbon dioxide in the atmosphere and the opticalcharacteristics is thus reduced.

Hereinafter, the light emitting device in which the aforementionedphosphors are used according to the present invention will be describedwith reference to the accompanying drawings.

FIG. 1 is a sectional view showing a first embodiment of the lightemitting device according to the present invention.

Referring to the figure, the light emitting device comprises a substrate10 and first and second electrodes 20 and 30 formed on the substrate 10.A light emitting diode 50 for emitting ultraviolet ray is mounted on thefirst electrode 20, and first and second phosphors 91 and 92, which areexcited by the ultraviolet ray to emit blue and green lights having peakwavelengths longer than the wavelength of the excitation light, arearranged over the first light emitting diode 50.

A second light emitting diode 60 is mounted on the second electrode 30,and emits red light different in wavelength from lights emitted from thefirst and second phosphors 91 and 92.

The first and second light emitting diodes 50 and 60 are commonly andelectrically connected to a third electrode (not shown) through wires100.

A molding portion 80 for encapsulating the first and second lightemitting diodes 50 and 60 is provided on the substrate 10, and the firstphosphor 91 for emitting blue light and the second phosphor 92 foremitting green light as described above are included in the moldingportion 80.

The substrate 10 may be formed with a predetermined groove around thecentral region of the substrate 10 through a mechanical processing, andthe groove may include a reflection portion (not shown) formed in such amanner that a sidewall surface thereof is inclined at a predeterminedslope.

The first and second light emitting diodes 50 and 60 are mounted on afloor surface of the reflection portion, so that the light emitted fromthe light emitting diode 20 can be maximally reflected to therebyincrease its luminous efficiency.

The molding portion 80 may be formed through an injection moldingprocess using a mixture of a predetermined transparent epoxy or siliconresin and the aforementioned phosphors 91 and 92. Alternatively, themolding portion 80 may be formed in such a manner that it ismanufactured using a separate mold and then pressurized or heat treated.The molding portion 80 may be formed into various shapes such as aconvex lens shape, a flat plate shape, and a shape having apredetermined concavo-convex surface.

At least any one of silicate based phosphor, germanate based phosphorand germanate-silicate based phosphor may be used as the first andsecond phosphors 91 and 92 which are included within the molding portion80 for encapsulating the first and second light emitting diodes 50 and60 on the substrate 10.

It is preferable that the phosphors 91 and 92 are uniformly distributedwithin the molding portion 80 as shown in the drawing, which causes thered light emitted from the second light emitting diode 60 and the blueand green lights emitted from the phosphors 91 and 92 to be uniformlymixed with each other, thereby implementing more uniform white light. Inorder to improve the color rendering, a phosphor (not shown) foremitting yellow light may be further included within the molding portion80.

In such a light emitting device according to the present invention, anexcitation light, i.e., light in the ultraviolet region is emitted fromthe light emitting diode 50 and causes the phosphors 91 and 92 to beexcited and emit excitation-emitted lights, and another light which isdifferent from the excitation-emitted lights is emitted from the secondlight emitting diode 60, so that the excitation light, theexcitation-emitted lights and the other light may be color-mixed toimplement colors in a required spectrum range.

That is, ultraviolet ray and red light are respectively emitted from theultraviolet and red light emitting diodes 50 and 60, and the ultravioletray allows the first and second phosphors 91 and 92 to emit blue andgreen lights, respectively, so that the color mixing thereof implementswhite light emission.

Accordingly, the red light emitting diode is used to improve an energyconversion efficiency of the white light emitting device on behalf ofthe red phosphor with a lower conversion efficiency in which the redphosphor is excited by a light energy of the excitation light source.

Further, using an ultraviolet light emitting diode with high energy ascompared with a blue light emitting diode having been used as theconventional excitation light source, the phosphors for emitting asmaller amount of blue and green lights are used to implement whitelight with the same intensity, thereby reducing its manufacturing costs.

Also, the red light emitting diode is used to solve the problem that thegenerally commercialized sulfide based red phosphor easily reacts withvapor and carbon dioxide in the atmosphere to reduce the opticalcharacteristics

FIG. 2 is a sectional view showing a second embodiment of the lightemitting device according to the present invention.

Referring to this figure, the light emitting device comprises asubstrate 10 and first and second electrodes 20 and 30 formed on thesubstrate 10. A light emitting diode 50 for emitting ultraviolet ray ismounted on the first electrode 20, and first and second phosphors 91 and92 which are excited by the ultraviolet ray to emit blue and greenlights having peak wavelengths longer than the wavelength of theexcitation light are arranged over the first light emitting diode 50.

A second light emitting diode 60 is mounted on the second electrode 30,and emits red light different in wavelength from lights emitted from thefirst and second phosphors 91 and 92.

A molding portion 80 for encapsulating the first and second lightemitting diodes 50 and 60 is provided on the substrate 10, and the firstphosphor 91 for emitting blue light, the second phosphor 92 for emittinggreen light and a scattering material 70 is contained within the moldingportion 80.

This is mostly identical with the constitutional features of the firstembodiment, and therefore, the overlapping specific descriptions will beomitted.

The first and second electrodes 20 and 30 are formed on the substrate10, and the first and second light emitting diodes 50 and 60 are mountedon the first and second electrodes 20 and 30, respectively. Unlike thefirst embodiment, the first and second light emitting diodes 50 and 60may be independently connected to third and fourth electrodes (notshown) through wires 100, respectively.

The molding portion 80 for encapsulating the first and second lightemitting diodes 50 and 60 is formed on the substrate 10. The first andsecond phosphors 91 and 92 and the scattering material 70 which areuniformly distributed are included in the molding portion 80.

The first and second phosphor 91 and 92 are the first phosphor 91 foremitting blue light and the second phosphor for emitting green light,both of which are excited by the ultraviolet ray used as the excitationsource as described above, and at least any one of silicate basedphosphor, germanate based phosphor and germanate-silicate based phosphormay be used as the first and second phosphors 91 and 92.

The scattering material 70 is added to further facilitate the colormixing of the lights, and particles whose dimension ranges from 0. 1 to20 μm are used as the scattering material 70. At least any one of SiO₂,Al₂O₃, TiO₂, Y₂O₃, CaCO₃ and MgO may be used as the scattering material70.

The light emitting device which includes the scattering material 70 mayscatter light emitted from the light emitting diodes 50 and 60 by thescattering material and the other lights from the phosphors 91 and 92,so that an unnecessary light emission pattern may not be formed and thelight may be uniformly emitted in a larger area. Accordingly, the lightshaving wavelengths different from each other are emitted in a largerarea to be uniformly mixed with each other, so that the light emittingdevice can implement the uniform white light.

FIG. 3 is a sectional view showing a third embodiment of the lightemitting device according to the present invention.

Referring to this figure, the light emitting device comprises asubstrate 10 and first and second electrodes 20 and 30 formed on thesubstrate 10.

A light emitting diode 50 for emitting ultraviolet ray is mounted on thefirst electrode 20, and first and second phosphors 91 and 92 which areexcited by the ultraviolet ray to emit blue and green lights having peakwavelengths longer than the wavelength of the excitation light arearranged over the first light emitting diode 50.

A second light emitting diode 60 is mounted on the second electrode 30,and emits red light different in wavelength from lights emitted from thefirst and second phosphors 91 and 92. This is mostly identical with theconstitutional features of the first embodiment, and therefore, theoverlapping specific descriptions will be omitted.

The light emitting device according to the this embodiment includes afirst molding portion 81 for encapsulating the first and second lightemitting diodes 50 and 60 on the substrate 10, and a second moldingportion 82 for covering the first molding portion 81, wherein the firstmolding portion 81 may be formed of silicon resin having a hardnesslower than that of the second molding portion 82. Accordingly, thermalstress applied to the first and second light emitting diodes 50 and 60and the wires 100 can be reduced. In order to prevent the first moldingportion 81 from being deformed by external force or the like, the secondmolding portion 82 may be formed of epoxy resin having relatively highhardness.

In this embodiment, the second phosphor 92 for emitting green light iscontained in the first molding portion 81 while the first phosphor 91for emitting blue light is contained in the second molding portion 82,so that light loss generated due to the re-absorption of the blue light,emitted from the first phosphor 91, into the second phosphor can beprevented.

FIG. 4 is a sectional view showing a fourth embodiment of the lightemitting device according to the present invention.

Referring to the figure, the light emitting device comprises a substrate10 and first and second electrodes 20 and 30 formed on the substrate 10.A light emitting diode 50 for emitting ultraviolet ray is mounted on thefirst electrode 20, and first and second phosphors 91 and 92 which areexcited by the ultraviolet ray to emit blue and green lights having peakwavelengths longer than the wavelength of the excitation light arearranged over the first light emitting diode 50.

A second light emitting diode 60 is mounted on the second electrode 30,and emits red light different in wavelength from lights emitted from thefirst and second phosphors 91 and 92. This is mostly identical with theconstitutional features of the third embodiment, and therefore, theoverlapping specific descriptions will be omitted.

The light emitting device according to this embodiment comprises a firstmolding portion 81, which includes the first and second phosphors 91 and92 and covers the first light emitting diode 50 for emitting ultravioletray, and a second molding portion 82 for encapsulating the first moldingportion 81 and the second light emitting diode 60.

Accordingly, it is possible to prevent light loss in which the red lightemitted from the second light emitting diode 60 is not emitted to theoutside of the first and second molding portions 81 and 82 butdisappears due to the first and second phosphor 91 and 92.

FIG. 5 is a sectional view showing a fifth embodiment of the lightemitting device according to the present invention.

Referring to this figure, the light emitting device comprises asubstrate 10 and first, second and third electrodes 30, 20 and 40 formedon the substrate 10. A light emitting diode 50 for emitting ultravioletray is mounted on the first electrode 20, and first and second phosphors91 and 92 excited by the ultraviolet ray to emit blue and green lightshaving peak wavelengths longer than the wavelength of the excitationlight are arranged over the first light emitting diode 50. This ismostly identical with the constitutional features of the fourthembodiment, and therefore, the overlapping specific descriptions will beomitted.

Second light emitting diodes 61 and 62 for emitting blue and red lightsare mounted on the second and third electrodes 20 and 40, respectively,wherein the wavelengths of the blue and red lights are different fromthat of the light emitted from the phosphor 90. As such, unlike theembodiment in which the phosphor is used as the blue light source, thelight emitting diode whose full width at half maximum (FWHM) is narrowis used to implement a light emitting device with an excellent colorreproduction which is significantly required to be used as a back lightsource for a liquid crystal display (LCD).

Of course, the present invention is not limited thereto, but the moldingportion 80 which includes the phosphor 90 for emitting green lightaccording to this embodiment is formed to cover the second lightemitting diode 61 for emitting blue light as well as the first lightemitting diode 50 for emitting ultraviolet ray. Accordingly, since thephosphor 90 can emit light by the blue light as well as the ultravioletray, the excitation power can be enhanced, thereby increasing greenlight emitted from the phosphor.

As such, the present invention can be adapted to products with variousconfigurations, and the technical features of the present invention arenot limited to the aforementioned embodiments but can be variouslymodified and adjusted.

For example, in case of a lamp-type light emitting device with leadterminals, after ultraviolet and red light emitting diodes are mountedon one lead terminal, a first molding portion which contains a phosphorto cover the ultraviolet light emitting diode is formed and a secondmolding portion for encompassing the ultraviolet and red light emittingdiodes and one end of the lead terminal is formed, in the similar manneras described above, thereby manufacturing the light emitting deviceaccording to the present invention.

Further, although a single blue light emitting diode chip and a singlered light emitting diode chip are used in the above embodiments, aplurality of chips may be used, if necessary.

1. A light emitting device, comprising: a first light emitting diode foremitting light in an ultraviolet wavelength region; at least onephosphor arranged around the first light emitting diode, the at leastone phosphor to be excited by the light emitted from the first lightemitting diode, and the at least one phosphor to emit light having apeak wavelength longer than the wavelength of the light emitted from thefirst light emitting diode; and at least one second light emitting diodefor emitting light having a wavelength different from the peakwavelength of the light emitted from the phosphor.
 2. The light emittingdevice as claimed in claim 1, wherein the phosphor comprises at leastany one of silicate based phosphor, germanate based phosphor, andgermanate-silicate based phosphor, and the each of phosphors comprisescopper.
 3. The light emitting device as claimed in claim 2, wherein atleast any one of silicate based phosphor germanate based phosphor andgermanate-silicate based phosphor further comprise lead.
 4. The lightemitting device as claimed in claim 1, wherein the phosphor comprises atleast any one of a first phosphor having its peak wavelength positionedin a range of 410 nm to 500 nm and a second phosphor having its peakwavelength positioned in a range of 500 nm to 590 nm.
 5. The lightemitting device as claimed in claim 1, wherein the phosphor comprises asilicate based phosphor represented by Chemical Formula 1:a(M^(I)O).b(M^(II)O).c(M^(III)A).d(M^(III) ₂O).e(M^(IV) ₂O₃).f(M^(V)_(o)O_(p)).g(SiO₂).h(M^(VI) _(x)O_(y)) where M^(I) is at least oneelement selected from the group containing Cu and Pb; M^(II) is at leastone element selected from the group consisting of Be, Mg, Ca, Sr, Ba,Zn, Cd and Mn; M^(III) is at least one element selected from the groupconsisting of Li, Na, K, Rb, Cs, Au and Ag; M^(IV) is at least oneelement selected from the group consisting of B, Al, Ga and In; M^(V) isat least one element selected from the group consisting of Ge, V, Nb,Ta, W, Mo, Ti, Zr and Hf; M^(VI) is at least one element selected fromthe group consisting of Bi, Sn, Sb, Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu,Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu; A is at least one element selectedfrom the group consisting of F, Cl, Br and I; a, b, c, d, e, f, g, h, o,p, x and y are set in ranges of 0<a≦2, 0<b≦8, 0≦c≦4, 0≦d≦2, 0≦e≦2,0≦f≦2, 0<g≦10, 0<h≦5, 1≦o≦2, 1≦p≦5, 1≦x≦2, and 1≦y≦5.
 6. The lightemitting device as claimed in claim 1, wherein the phosphor comprises agermanate and/or germanate-silicate based phosphor represented byChemical Formula 2:a(M^(I)O).b(M^(II) ₂O).c(M^(II)A).dGeO₂ e(M^(III)O).f(M^(IV)₂O₃).g(M^(V) _(o)O_(p)).h(M^(VI) _(x)O_(y)), where M^(I) is at least oneelement selected from the group containing Cu and Pb; M^(II) is at leastone element selected from the group consisting of Li, Na, K, Rb, Cs, Auand Ag; M^(III) is at least one element selected from the groupconsisting of Be, Mg, Ca, Sr, Ba, Zn, Cd and Mn; M^(IV) is at least oneelement selected from the group consisting of Sc, Y, B, Al, Ga, In andLa; M^(V) is one or more elements selected from the group consisting ofSi, Ti, Zr, Mn, V, Nd, Ta, W and Mo; M^(VI) is at least one elementselected from the group consisting of Bi, Sn, Pr, Sm, Eu, Gd, Dy and Tb;A is at least one element selected from the group consisting of F, Cl,Br and I; a, b, c, d, e, f, g, h, o, p, x and y are set in ranges of0<a≦2, 0≦b≦2, 0≦c≦10, 0<d≦10, 0≦e≦14, 0≦f≦14, 0≦g≦10, 0≦h≦2, 1≦o≦2,1≦p≦5, 1≦x≦2, and 1≦y≦5.
 7. The light emitting device as claimed inclaim 1, wherein the second light emitting diode comprises a lightemitting diode for emitting light having a wavelength longer than thepeak wavelength of the light emitted from the phosphor.
 8. The lightemitting device as claimed in claim 7, wherein the second light emittingdiode comprises a light emitting diode for emitting light in awavelength range of 590 nm to 720 nm.
 9. The light emitting device asclaimed in claim 7, wherein the second light emitting diode furthercomprises a light emitting diode for emitting light in a wavelengthrange of 420 nm to 480 nm, the wavelength being shorter than the peakwavelength of the light emitted from the phosphor.
 10. The lightemitting device as claimed in claim 1, further comprising: a substrate;and a first electrode and a second electrode arranged on the substrate,the first light emitting diode and the second light emitting diode beingrespectively disposed on the first electrode and the second electrode.11. The light emitting device as claimed in claim 10, further comprisinga molding portion arranged on the substrate, the molding portionencapsulating, the first light emitting diode and the second lightemitting diode, wherein the molding portion comprises the phosphor. 12.The light emitting device as claimed in claim 11, wherein the moldingportion further comprises a scattering material.
 13. The light emittingdevice as claimed in claim 10, further comprising a first moldingportion and a second molding portion arranged on the substrate, thefirst molding portion encapsulating the first light emitting diode,wherein the first molding portion comprises the phosphor, the secondmolding portion encapsulating the second light emitting diode.
 14. Thelight emitting device as claimed in claim 13, wherein the second lightemitting diode is for emitting light having a wavelength longer orshorter than the peak wavelength of the light emitted from the phosphor.